1,3-Dioxan-2-one CAS#2453-03-4

1.Key Monomer for Biodegradable Polymers: An essential monomer for synthesizing poly(trimethylene carbonate) (PTMC), a biodegradable polymer ideal for advanced material applications.

2.Excellent Organic Solvent Solubility: Readily soluble in organic solvents like methanol, ensuring smooth integration into various chemical synthesis processes.

3.Clear Physical Specifications: Supplied as white to off-white crystals with a melting point of 45–47°C, allowing for precise identification, handling, and quality control.

4.Optimized for Polymer Synthesis: Its unique cyclic carbonate structure makes it a highly effective starting material for producing PTMC and related polymers under controlled conditions.

Products Description of 1,3-Dioxan-2-one CAS#2453-03-4

1,3-Dioxan-2-one (TMC) is a cyclic carbonate compound with the molecular formula C₄H₆O₃ and CAS number 2453-03-4. It is mainly used as a monomer in the synthesis of poly(trimethylene carbonate) (PTMC), a biodegradable polymer. This compound typically appears as white to off-white crystals and has a melting point of 45–47°C. It is readily soluble in organic solvents, including methanol. For proper storage and stability, it should be kept at a low temperature of 2–8°C under an inert gas atmosphere.

1,3-Dioxan-2-one CAS#2453-03-4

1,3-Dioxan-2-one Chemical Properties

English Name1,3-Dioxan-2-one
English Synonyms1,3-Dioxan-2-one;1,3-Propylene carbonate;1,3-Propanediol cyclic carbonate;Carbonic acid 1,3-propanediyl ester;trimethylene carbonate1,3-Dioxan-2-one;1,3-Dioxan-2-one> Trimethylene carbonate (TMC) ,99%;TIA NFU-CHEM CAS NO.2453-03-4 1,3-Dioxan-2-one
CAS Number2453/3/4
Molecular FormulaC4H603
Molecular Weight102.09
EINECS Number607-395-4
Melting point 45.0 to 49.0 °C
Boiling point 135°C/4mmHg(lit.)
density 1.200±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility soluble in Methanol
form powder to crystal
color White to Almost white
Risk Statements 22-36
Safety Statements 24/25
InChIInChl=1S/C4H603/c5-4-6-2-1-3-7-4/h1-3H2
InChIKeyYFHICDDUDORKJB-UHFFFAOYSA-N
SMILES01CCCOC1=0

Primary Applications

  • Ring-Opening Polymerization: 1,3-Dioxan-2-one is used in bulk ring-opening polymerization initiated by butyltin chlorides (BuSnCl, Bu₂SnCl, or Bu₃SnCl) to produce poly(trimethylene carbonate) (PTMC).

  • Copolymerization and Material Modification: It can be copolymerized with monomers such as ε-caprolactone or L-lactide to adjust the mechanical properties, degradation rate, and thermodynamic behavior of the resulting materials, making it promising for biomedical applications.

  • Homopolymer and Crosslinked Material Applications: PTMC can also be copolymerized with other lactone monomers. Following crosslinking, it can form a flexible, elastic network with properties similar to those of polydimethylsiloxane (PDMS) rubber.

1,3-Dioxan-2-one CAS#2453-03-4

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